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IUPAC Nomenclature Problem 1


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Published on:  on 10th Apr, 2018

Description:

Give the IUPAC name of the given halides and classify them as primary, secondary and tertiary halides.

a) CH3C(C2H5)2CH2Br

b) p − ClC6H4CH2CH(CH3)2

c) CH3CH = C(Cl)CH2CH(CH3)2

d) CH3CH = CH(C)Br(CH3)2

Solution

a) CH3C(C2H5)2CH2Br

IUPAC Name

1 − Bromo − 2 − ethyl − 2 − methylbutane

Primary alkyl halide.

Primary Alkyl Halide

b) p − ClC6H4CH2CH(CH3)2

IUPAC Name − 1 − Chloro − 4 − (2 − methylpropyl)benzene

Aryl Halide

Alkyl Halide

c) CH3CH = C(Cl)CH2CH(CH3)2

IUPAC Name − 3 − Chloro − 5 − methylhex − 2 − ene

Vinyl Halide

  • −Cl attached to sp2 carbon atom.

Vinyl Halide

d) CH3CH = CH(C)Br(CH3)2

Structure

Allyl Halide

IUPAC Name − 2 − Bromo − 2 − methylpent − 3 − ene.

Allyl Halide

  • Carbon attached to sp3 carbon adjacent to a double bond.


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